Electrocatalytic Activation of Donor–Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(sp 3 )−C(sp 3 ) Cleavage Mode
نویسندگان
چکیده
منابع مشابه
Palladium-catalyzed homocoupling reactions between two Csp(3)-Csp(3) centers.
[reaction: see text] A novel palladium-catalyzed coupling reaction between two Csp(3)-Csp(3) centers has been investigated. This protocol is initiated by the oxidative addition of an alpha-halo carbonyl compound to a palladium(0) species, followed by the double transmetalation. The key dialkyl palladium intermediate undergoes reductive elimination to form the desired coupling product.
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2021
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.202101477